Adsorption of Supercritical Carbon Dioxide on Silica
✍ Scribed by Di Giovanni, Orazio; Dörfler, Werner; Mazzotti, Marco; Morbidelli, Massimo
- Book ID
- 120363003
- Publisher
- American Chemical Society
- Year
- 2001
- Tongue
- English
- Weight
- 135 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0743-7463
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Adsorption isotherms were determined for methanol and 1-hexanol on silica from supercritical carbon dioxide at four temperatures and three mobile phase densities. Maximum stationary phase concentrations were extrapolated from linear least squares fits of the data to the Langmuir equation for monolay
## Abstract Supercritical fluids are attractive solvents for heterogeneous processes, including catalysis and adsorptive separation. However, adsorption processes in the near‐critical region are poorly understood and exhibit unique behavior where the adsorption of the supercritical solvent plays an