At 1.5 V applied between the electrodes on the piezoelectric crystal, many metals electrodeposit on an electrode so that the frequency changes. Iron(II1) (1 X lo-'-1 x 1O-4 M) can be determined by adsorption of iron(II1) phosphate which also causes a frequency change. Electrodeposition can be preven
Adsorption of metal ions from solutions on the quartz plate of an electrode-separated piezoelectric quartz crystal
β Scribed by Toshiaki Nomura; Mie Isawa; Hiromi Matsuzawa; Yoko Shibukawa
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 648 KB
- Volume
- 286
- Category
- Article
- ISSN
- 0003-2670
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β¦ Synopsis
Metal ions were adsorbed on the quartz plate of an electrode-separated piezoelectric quartz crystal in solution. The substances adsorbed were hydroxides. Only a few metal ions adsorbed in solutions of higher ionic strength, but a quartz plate coated with Teflon adsorbed many metal ions and had a higher sensitivity, that is, it could be used for the determination of small amounts of metal ions.
π SIMILAR VOLUMES
The adsorption and electrocatalytic oxidation of carbon monoxide on platinum was studied in both acid and alkaline supporting electrolytes using an electrochemical quartz crystal microbalance. Depending on the pH of the medium, a significant influence of CO on the electrode mass was observed, partic