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Adsorption of Complexes of Cations of Alkali Metals with a Macrocyclic Ligand (Kryptofix® 222) on a Mercury Electrode

✍ Scribed by E. V. Stenina; O. A. Baturina; L. N. Sviridova; B. B. Damaskin

Book ID
110345523
Publisher
SP MAIK Nauka/Interperiodica
Year
2002
Tongue
English
Weight
139 KB
Volume
38
Category
Article
ISSN
1023-1935

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## Abstract The complexation kinetics of the two macrocycles **1** and **2** with Co^2+^, Ni^2+^, Cu^2+^ and Zn^2+^ have been measured by pH‐stat techniques. The rates are first order in metal and ligand concentration and depend upon the pH. This results from the different reactivities of the vario