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Adsorption of associating and non-associating adsorbates on microporous carbon adsorbents

✍ Scribed by Michał Rozwadowski; Kazimierz E. Wiśniewski; Roman Wojsz

Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
891 KB
Volume
22
Category
Article
ISSN
0008-6223

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✦ Synopsis

The adsorption of different chemical substances on microporous carbon adsorbents has been investigated. It has been determined that the chemical character of the molecules adsorbed as well as the adsorbent texture determine the adsorption kinetics. In the case of alcohols, one of the parameters determining the sorption mechanism is the formation of complexes. As was shown earlier, the rates of complex molecule formation for methyl and ethyl alcohols differ significantly.

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✍ M.M. Dubinin 📂 Article 📅 1987 🏛 Elsevier Science 🌐 English ⚖ 619 KB

The theory underlying the absorption behavior of carbons is discussed as a basis for quantitative analysis of their adsorption properties and microporous structure. The equations of the theory of volume filling of micropores for homogeneous and inhomogeneous microporous structures and a rational me