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Adsorption of amines and ammonia on H+-form ion exchanger

✍ Scribed by Hiroyuki Yoshida; Takeshi Kataoka


Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
878 KB
Volume
42
Category
Article
ISSN
0009-2509

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✦ Synopsis


Equilibrium isotherms for adsorption of ten representative amines including ammonia on two different H+-form ion exchangers have been determined in order to assess the possibility of using such a system to recover amines from industrial waste-water. The selectivity was very high. Equilibria for the C,-C, amines were correlated by an equation derived according to the mass action law while the isotherms for the C&Z,, species were of Freundlich form. Intraparticle diffusivities for linear and non-linear amines were measured and the effects of the molecular weight and molecular shape on the diffusivity are discussed. A simple empirical equation correlating diffusivity with the maximum molecular chain length is suggested.


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