Equilibrium isotherms and kinetic data for sorption of ethylamine on two different H-form ion exchangers (a homogeneous gel type and a biporous MR type) have been determined experimentally by the gravimetric method. The gaseous amine is adsorbed on the dry resins according to an acid-base neutraliza
Adsorption of amines and ammonia on H+-form ion exchanger
β Scribed by Hiroyuki Yoshida; Takeshi Kataoka
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 878 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0009-2509
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β¦ Synopsis
Equilibrium isotherms for adsorption of ten representative amines including ammonia on two different H+-form ion exchangers have been determined in order to assess the possibility of using such a system to recover amines from industrial waste-water. The selectivity was very high. Equilibria for the C,-C, amines were correlated by an equation derived according to the mass action law while the isotherms for the C&Z,, species were of Freundlich form. Intraparticle diffusivities for linear and non-linear amines were measured and the effects of the molecular weight and molecular shape on the diffusivity are discussed. A simple empirical equation correlating diffusivity with the maximum molecular chain length is suggested.
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