Adsorption Mechanisms of Charged, Amphiphilic Diblock Copolymers: The Role of Micellization and Surface Affinity
β Scribed by Toomey, Ryan; Mays, Jimmy; Holley, D. Wade; Tirrell, Matthew
- Book ID
- 124060608
- Publisher
- American Chemical Society
- Year
- 2005
- Tongue
- English
- Weight
- 142 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0024-9297
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π SIMILAR VOLUMES
## Abstract The selfβassembly of PVPhβ__b__βPS in different solvents was studied. Upon replacing toluene by THF as the solvent, the morphology of the resulting aggregates change from coreβshell spheres, rodβlike micelles and vesicles to onionβlike aggregates. With increasing block copolymer concent
In this work the evolution of the surface concentration, surface potential, and surface tension for adsorption of a charged amphiphile at an interface is studied numerically. While the results are of interest for any amphiphile, the simulations are performed for typical surfactant material parameter