Adsorption Isotherms and Linear Gas-Solid Chromatography
β Scribed by SCOTT, C. G.
- Book ID
- 109619400
- Publisher
- Nature Publishing Group
- Year
- 1962
- Tongue
- English
- Weight
- 190 KB
- Volume
- 193
- Category
- Article
- ISSN
- 0028-0836
- DOI
- 10.1038/193159a0
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π SIMILAR VOLUMES
sorption isotherms, (1) which is illustrated in Fig. 1. Type Adsorption at fluid-solid interfaces is considered in the frame-I isotherms are characteristic of microporous adsorbents. work of a lattice with boundaries. Using ideas proposed by S. Types II and III describe adsorption on macroporous ads
Based on a modified form of the Gibbs equation, two conditions of thermodynamical correctness have been defined. According to these conditions the change in the free energy of the surface-calculable from all isotherm equations-must have finite limiting values at \(\theta \rightarrow 0\) and \(\theta