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Adsorption-based characterization of hierarchical metal–organic frameworks

✍ Scribed by Villemot, François; Galarneau, Anne; Coasne, Benoit

Book ID
121545076
Publisher
Springer
Year
2013
Tongue
English
Weight
835 KB
Volume
20
Category
Article
ISSN
0929-5607

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## Abstract __Interaction between adsorbed hydrogen and the coordinatively unsaturated Mg^2+^ and Co^2+^ cationic centres in Mg‐MOF‐74 and Co‐MOF‐74, respectively, was studied by means of variable‐temperature infrared (VTIR) spectroscopy. Perturbation of the H~2~ molecule by the cationic adsorbing