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Ado method of treating ion-dipole molecule collisions

โœ Scribed by D.R Bates

Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
198 KB
Volume
82
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

The average dipole orientation method requires knowledge of the instantaneous rotational energy of the neutral molecule. It is wrong to seek to determine this by appeal to ener,7 conservation. The correct procedure depends on the adiabatic xmariance of #ipdq/Zs_ An analytic approximation IS Introduced which gwes the rate coefficient accurately when Z&T/D' is small.

๐Ÿ“œ SIMILAR VOLUMES

Ion-dipole collisions: Ado treatment
Ion-dipole collisions: Ado treatment
โœ D.R. Bates ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 153 KB

discrcqmcy between a formula derived by Sakimoto and the ADO treatment is resolved. ## 1. introduction Su and Bowers [1,2] initiated research on a physically appealing method of calculating the rate coeffcient for ion-dipole hitting collisions: their average-

Ion-polar molecule collisions. A modific
Ion-polar molecule collisions. A modification of the average dipole orientation theory: The cos ฮธ model
โœ L. Bass; T. Su; W.J. Chesnavich; M.T. Bowers ๐Ÿ“‚ Article ๐Ÿ“… 1975 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 307 KB

The average dipole orientation (AEO) theory of ion-polar molecule apiure collisions is reformuhta3 in terms of the average cosine, cos0. The earlier formulation USA an average angle, S, in the effective potential that is used to develop cxpressions for the cross section and rzte constant. The cos 0