We consider electrochemical electron transfer reactions, where the rate is limited by the electron transfer process. We suggest a diffusion-reaction equation approach to the problem. The electron transfer from an ion in solution to the metal would occur as soon as the energy of the orbital on the io
Adiabaticity in electrochemical electron transfer: a perspective from a diffusion-reaction equation approach
β Scribed by K.L. Sebastian; Nalini Chakravarti
- Publisher
- Elsevier
- Year
- 1993
- Tongue
- English
- Weight
- 248 KB
- Volume
- 351
- Category
- Article
- ISSN
- 1572-6657
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The effect of pressure-induced changes in solvent viscosity on the kinetics of intermolecular electron transfer between eleo tronically excited 9,lO-diphenylanthracene and maleic anhydride in acetonitrile was investigated using time-resolved fluorescence measurements. The nonexponential fluorescence
Results are reported from uv-vis absorption measurements in the diffusion layers of planar, cylindrical and spherical electrodes. The reversible one-electron oxidation/reduction processes of N,N,N', N'-tetramethyl-p-phenylendiamine have been used as an example. Diffusion coefficients and formal rate