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Adiabatic-to-diabatic electronic state transformation and curvilinear nuclear coordinates for molecular systems

✍ Scribed by Xavier Chapuisat; André Nauts; Dominique Dehareng-Dao


Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
416 KB
Volume
95
Category
Article
ISSN
0009-2614

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✦ Synopsis


Following an original idea of Bacr, since then several times applied to various small molecular collisional systems. it is shown that -whatever the choice of Curvilinear generalized coordinates to describe the molecular gometry and owxall rotation -the algebraic fmmework proposed by Baer remains valid provided only that the esnct tensorhl expression of the kinetic energy operator is used.