✦ LIBER ✦
Adiabatic ionization energies from charge transfer equilibrium constants; experimental determinations of entropy changes for charge transfer equilibria
✍ Scribed by Sharon G. Lias
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- English
- Weight
- 484 KB
- Volume
- 54
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
Equihbrium constants have been mc,~surcd as d function of temperature for the char!ze trdnsfcr cquihbria in mP.turrs of NO with aromatic compounds, and mixtures of azomatlc compounds. The experimentally determined entropy changes are in good agreement with entropy changes ckulatcd from statistical mechanical considerations provided an intermolecular component IS included. l%c enthalpy ch~gcs for the charge trnncfer reactions correspond to the drfferenceb m the adiabatic ionizatron potentials of the compounds. ') All literature data from ref. 191.