Adiabatic Heteronuclear Decoupling in Rotating Solids
✍ Scribed by Jörg Leppert; Oliver Ohlenschläger; Matthias Görlach; Ramadurai Ramachandran
- Book ID
- 111591470
- Publisher
- Springer Netherlands
- Year
- 2004
- Tongue
- English
- Weight
- 191 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0925-2738
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The mechanism of heteronuclear dipolar decoupling by the TPPM sequences, proposed by Bennett et al. (J. Chem. Phys. 103 (1995) 6951) is investigated by comparison with a modified pulse sequence, called TPFM, that uses frequency instead of phase modulation. By combining frequency and phase modulation
## Abstract For Abstract see ChemInform Abstract in Full Text.
Coherence transfer by an isotropic mixing process is used for two-dimensional heteronuclear shift correlation in magicanple-spin&q solid-state spectroscopy. Selective coherence transfer is conlbiied with efficient homonuclear and hereronuclear dipolar decoupling to obtain well-resolved shift corre!n