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Addukte aus dem Keten (1E,3Z)-1,2,3,4,5-Pentamethyl-6-oxo-1,3,5-hexatrienylacetat

✍ Scribed by Prof. Dr. Gerhard Quinkert; Uta-Maria Billhardt; Dr. Erich F. Paulus; Dr. Jan W. Bats; Prof. Dr. Hartmut Fuess

Publisher
John Wiley and Sons
Year
1984
Tongue
English
Weight
319 KB
Volume
96
Category
Article
ISSN
0044-8249

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The reaction of (C 5 Me 5 ) 2 Si or (C 5 Me 5 )SiMe 3 with B 2 Cl 4 leads to the adducts (C 5 Me 5 )BǞBCl 2 SiCl 3 (5a) or (C 5 Me 5 )BǞBCl 3 (5b), in which the Lewis acids stabilize the boranediyl frag- [a] Anorganisch-