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Adducts of o-Silaborane With Water and Methanol

✍ Scribed by Lars Wesemann; Michael Trinkaus; Yves Ramjoie; Beate Ganter; Ulli Englert; Jens Müller

Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
295 KB
Volume
2000
Category
Article
ISSN
1434-1948

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✦ Synopsis

The synthesis of alkoxide adducts of o-silaborane Me 2 Si 2 B 10 H 10 ) 2 O] (3) and[TMPDAH][(Me 2 -Si 2 B 10 H 10 )OMe] (4) are presented (TMPDA = tetramethylpropylenediamine). For both silaborate clusters 3 and 4 the results of the NMR spectroscopic investigations together with the X-ray single crystal structure determinations are discus-

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