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Adducts of Ferrocenylboranes and Pyridine Bases: Generation of Charge-Transfer Complexes and Reversible Coordination Polymers

✍ Scribed by Marco Fontani; Frank Peters; Wolfgang Scherer; Wolfgang Wachter; Matthias Wagner; Piero Zanello


Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
18 KB
Volume
1998
Category
Article
ISSN
1434-1948

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Adducts of Ferrocenylboranes and Pyridin
✍ Marco Fontani; Frank Peters; Wolfgang Scherer; Wolfgang Wachter; Matthias Wagner 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 348 KB

Compared to parent ferrocene, the redox potential of the with 2 equiv. of 1. 1•bipy•1 has been structurally characterized by X-ray crystallography. The compound Fe II /Fe III transition is shifted to much more cathodic values in B-N adducts 1•Do and 2•(Do) 2 of borylated ferrocenes tolerates loss of