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Adducts of copper(II) acetate with amines in ethanolic solution

✍ Scribed by Ralf Giesse; Yoshitaka Gushikem; Pedro L.O. Volpe

Publisher: Elsevier Science
Year: 1982
Tongue: English
Weight: 379 KB
Volume: 54
Category: Article
ISSN: 0040-6031
DOI: 10.1016/0040-6031(82)80015-4

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✦ Synopsis

Copper(H) acctatc was calorimetrically titrated with pyridine , I-. 3-and 4-mcthylp~ridinc in absolute ethanol. The enthalpy of reaction and the equilibrium constant were determined for the adduct fornxttion in solution for each ligand. The aminci react with copper(H) acetate without breaking the dimcric structure at least in the limit of the concentration ratiolligandI/I(CH3C0,),Cu,I<:.

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