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Additive Effects in Palladium—Indium Mediated Barbier-type Allylations.

✍ Scribed by Laura A. T. Cleghorn; Ian R. Cooper; Ronald Grigg; William S. MacLachlan; Visuvanathar Sridharan


Book ID
101957581
Publisher
John Wiley and Sons
Year
2004
Weight
140 KB
Volume
35
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


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A new diastereo-and regioselective Pd/In bimetallic cascade process which assembles three contiguous chiral centres is described. Pd(0)-catalysed cyclisation of aryl iodides onto proximate 1,3-dienes generates p-allylpalladium(II) species, transmetallation with indium and subsequent Barbier-type add