Additive Effects in Palladium—Indium Mediated Barbier-type Allylations.
✍ Scribed by Laura A. T. Cleghorn; Ian R. Cooper; Ronald Grigg; William S. MacLachlan; Visuvanathar Sridharan
- Book ID
- 101957581
- Publisher
- John Wiley and Sons
- Year
- 2004
- Weight
- 140 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
For Abstract see ChemInform Abstract in Full Text.
📜 SIMILAR VOLUMES
Barbier-type allylation of unactivated aldimines with allyl bromides in the presence of indium powder took place rapidly in alcoholic solvents to give homoallylic amines in fair to good yields.
A new diastereo-and regioselective Pd/In bimetallic cascade process which assembles three contiguous chiral centres is described. Pd(0)-catalysed cyclisation of aryl iodides onto proximate 1,3-dienes generates p-allylpalladium(II) species, transmetallation with indium and subsequent Barbier-type add
## Abstract For Abstract see ChemInform Abstract in Full Text.