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Additions of substituted phenylthiyl radicals to substituted α-methylstyrenes : Ground state and transition state electronic effects

✍ Scribed by Brian N. Geers; Gerald Jay Gleicher; Daniel F. Church


Publisher
Elsevier Science
Year
1980
Tongue
French
Weight
400 KB
Volume
36
Category
Article
ISSN
0040-4020

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Zinc(II) complexes of substituted tetraphenylporphyrins, Zn[T(X-P)P], where X = H, p-F, p-Cl, m-Cl, p-CH 3 O, and m-CH 3 O, have been synthesized and characterized. Peripheral substitution shows marked changes in the chemical shifts of the phenyl proton resonances and E 1/2 values of the redox coupl