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Additions and Corrections - The Synthesis of Condensed Ring Compounds. XVII. Total Synthesis of a 10a-Methyldodecahydrochrysene-1,4-dione (a 10-Methyl-D-homosteradiene-15,17a-dione)

✍ Scribed by Gaddis, Adam; Butz, Lewis


Book ID
127308559
Publisher
American Chemical Society
Year
1947
Tongue
English
Weight
123 KB
Volume
69
Category
Article
ISSN
0002-7863

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Experiments on the Total Synthesis of Ly
✍ Rudolf O. Duthaler; Peter Mathies; Walter Petter; Christoph Heuberger; Veronica πŸ“‚ Article πŸ“… 1984 πŸ› John Wiley and Sons 🌐 German βš– 265 KB

## Abstract The substituted 1,2,3,4,4a,9,10,10a‐octahydrophenanthrene‐4,9‐dione **2**, synthesized from the cyclohexanone **8** and quinone __11__ (__Scheme 2__), was found by X‐ray analysis adn ^1^H‐NMR studies to be the isomer with __cis__‐junction of the saturated rings. The __cis__‐fusion could