Additions and Corrections - The Kinetics and Mechanism of the Reaction of Cerium(IV) and Chromium(IV)
β Scribed by King, Edward L.
- Book ID
- 126093983
- Publisher
- American Chemical Society
- Year
- 1962
- Tongue
- English
- Weight
- 130 KB
- Volume
- 84
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
Kinetics and mechanism of the cerium(1V) oxidation of Cr(II1) complexes of a series of macrocyclic (or pseudomacrocyclic) ligands with L14l-membered intraligand rinqsizes have now been investigated at I = 1.0 Tvf !LiClO.d Temp. 30Β°C. The complexes of' the formulation Cr(macrocycle)(X)(H20)'3 ''I-whe
The cerium(IV) oxidation of isobutanol, isoamyl alcohol isopropyl alcohol, and secondary butanol catalysed by chromium(III) was studied in sulphuric and perchloric acid mixture at 30 Β°C. The reaction was found to proceed with the formation of a chromium(IV) intermediate followed by its complexation