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Additions and Corrections - The Formation of Cyclic Acetals from Aldehydes or Ketones and Alkylene Oxides

✍ Scribed by Bogert, Marston; Roblin, Jr, Richard


Book ID
127172080
Publisher
American Chemical Society
Year
1933
Tongue
English
Weight
73 KB
Volume
55
Category
Article
ISSN
0002-7863

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N,N-dimethylhydrazones of aldehydes can be efficiently oxidized in a catalytic way by hydrogen peroxide associated with methyltrioxorhenium (MTO) as the catalyst to give nitriles. Elimination of dimethylhydroxylamine that is further oxidized to N-methyl-N-methylene N-oxide takes place. This nitrone