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Additions and Corrections - The Alkylation of Diazoacetonitrile and Ethyl Diazoacetate by Means of Organoboranes. A New Synthesis of Nitriles and Esters

โœ Scribed by Hooz, John; Linke, Siegfried


Book ID
127226048
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
135 KB
Volume
91
Category
Article
ISSN
0002-7863

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Lewis acid-catalyzed reactions of ethyl
โœ Shuji Kanemasa; Toshio Kanai; Takahiro Araki; Eiji Wada ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 255 KB

Ethyl diazoacetate reacts with a variety of aldehydes in the presence of a Lewis acid catalyst to give either [~-keto esters or a-formyl esters, the types of products mainly depending upon the nature of Lewis acid catalysts employed. Reactions catalyzed by Lewis acids such as SnCI2 and SnCl4 provide