Additions and Corrections - Silanes in Organic Synthesis. 8. Preparation of Vinylsilanes from Ketones and Their Regiospecific Cyclopentenone Annulation.

Functionalized Nitroalkanes in Organic S

Functionalized Nitroalkanes in Organic Synthesis. The first concise preparation of 4-hydroxyheptadecan-7-one and 14-hydroxyoctadecan-8-one, two new hydroxy ketones isolated from Chiococca alba

✍ Roberto Ballini; Giovanna Bosica; Gianni Rafaiani 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 German ⚖ 242 KB

## Abstract The 4‐hydroxyheptadecan‐7‐one (1) and 14‐hydroxyoctadecan‐8‐one (2), two new hydroxyketones isolated from leaves of __Chiococca alba__, were synthesized, for the first time, by hydroxy‐functionalized nitroalkanes 4 and 9, respectively, __via__ two chemoselective key steps: __i__) nitroa