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Additions and Corrections: Cyclopropyl Ketones. I. Synthesis and Spectra of 1-Aroyl-2-arylcyclopropanes.

โœ Scribed by Mohrbacher, Richard; Cromwell, Norman


Book ID
126298297
Publisher
American Chemical Society
Year
1957
Tongue
English
Weight
262 KB
Volume
79
Category
Article
ISSN
0002-7863

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Stereospecific 1,2-rearrangement of cycl
โœ Masato Shimazaki; Hisaaki Hara; Keisuke Suzuki ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 294 KB

Stereospecific 1,2-rearrangement of cyclopropyl group is described as an efficient route to stereo-defined a-cyclopropyl ketones and cr-cyclopropyl aldols. Acceleration of the reaction by the introduction of trimethylsilyl (TMS) group to the a-position of cyclopropyl group is also noted. ## Cyclop