Additions and Corrections - Cycloadditions with Heterocycles. Reactions of tert-Butylcyanoketene with 2-(Dimethylamino)thiazoles.
β Scribed by Dondoni, Alessandro; Medici, Alessandro; Venturoli, Clara; Forlani, Luciano; Bertolasi, Valerio
- Book ID
- 126271873
- Publisher
- American Chemical Society
- Year
- 1980
- Tongue
- English
- Weight
- 120 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
+ 2) Cycloaddition / Zwitterion formation / Ketene aminal l,l-Bis(dimethylamino)-1,3-butadiene (1) as a strong donor diene = 0.03 V vs. SCE, 1st IP, = 6.94 eV) is treated with acrylonitrile, dimethyl dicyanofumarate, and tetracyanoethylene. Cycloaddition with acrylonitrile is slow and requires eleva
The reactions of q5-CsHs Fe(CO)2 CH,GCR (R = CH3, C&, and CH,Fe(CO)2($-CsHs)), $-C,Hs-Mo(CO), CH, CXC, H5, and Mn(CO)s CH, CWC, H5 ( [M] CH, ECR) with the ketenes (C6Hsjz C=C=O and (t-C4H9)(CN)C=CL-0 and with the N-sulfinyl compounds C, Hs N=S=O and p-CH3 C6H4S0, N= S=O result in the formation of (3