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Additions and Corrections - Allylcarbinyl-Cyclopropylcarbinyl Norbornenyl-Nortricyclyl Anion Rearrangement. Evidence for a Symmetrical Intermediate.

✍ Scribed by Stille, J. K.; Sannes, K. N.

Book ID: 127169444
Publisher: American Chemical Society
Year: 1973
Tongue: English
Weight: 137 KB
Volume: 95
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00784a609

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📜 SIMILAR VOLUMES

Allylcarbinyl-cyclopropylcarbinyl norbor

Allylcarbinyl-cyclopropylcarbinyl norbornenyl-nortricyclyl anion rearrangement. Evidence for a symmetrical intermediate

✍ Stille, J. K.; Sannes, K. N. 📂 Article 📅 1972 🏛 American Chemical Society 🌐 English ⚖ 306 KB

The Cyclopropylcarbinyl-Cyclobutyl-Homoa

The Cyclopropylcarbinyl-Cyclobutyl-Homoallylic Rearrangement. Part III. Evidence for a symmetrical intermediate and for two discrete rearrangement processes

✍ Manfred Geisel; Cyril A. Grob; René P. Traber; Werner Tschudi 📂 Article 📅 1976 🏛 John Wiley and Sons 🌐 German ⚖ 879 KB

## Abstract In buffered 70% aqueous dioxane the cyclopropylcarbinyl (**1**‐X), __endo__‐cyclobutyl (**2**‐X) and homoallylic (**3**‐X) derivatives (X = nucleofuge) react to give the same mixture of alcohols **1**‐OH and **3**‐OH by way of a common intermediate, the symmetrical homoallylic ion **22*