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Additions and Corrections - A Sigmatropic Rearrangement Involving Dimethyl Sulfoxide during an Oxidation of a Carbohydrate Derivative

✍ Scribed by Nagarajan, Srinivasan; Rinehart, Jr., Kenneth


Book ID
121278464
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
106 KB
Volume
50
Category
Article
ISSN
0022-3263

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The reaction of aminomethyl dimethylphosphine oxide and (1 R)Β±(+)-camphor furnished the r 4 k 5 -P Schiff base 1. Reduction of 1 with trichlorosilane, followed by alkaline hydrolysis, led to 2-bornanylen(dimethylphosphino)methyl imine 2. The 1,2-r 5 k 5 oxaphosphetane 5, formed in the reaction of 2