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Addition Reactions of Benzenesulfinic Acid with Glycals and 1,2-Dibromosugars

✍ Scribed by Basava, Vikram; Flores, Broc; Giovine, Matthew; Licisyn, Thomas; Walck, Katelyn; Boyko, Walter; Giuliano, Robert

Book ID: 121327694
Publisher: Taylor and Francis Group
Year: 2008
Tongue: English
Weight: 452 KB
Volume: 27
Category: Article
ISSN: 0732-8303
DOI: 10.1080/07328300802374805

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Only a few reports deal with Diels-Alder or 1,3-dipolar cycloaddition reactions of glycals . For instance, azodicarboxylates undergo Diels-Alder cycloaddition with glycals to afford oxadiazines [2 -9]. The method allows the stereoselective introduction of a nitrogen atom on C-2 of a carbohydrate, an