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Addition of Secondary Amines to Dibromopropanol

โœ Scribed by Whitmore, Frank C.; Mosher, Harry S.; Spalding, David P.; Taylor, Robert B.; Moersch, George W.; Yanko, William H.


Book ID
126110471
Publisher
American Chemical Society
Year
1946
Tongue
English
Weight
286 KB
Volume
68
Category
Article
ISSN
0002-7863

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Addition of secondary amines to alkynylp
โœ Anna E. Panarina; Alla V. Dogadina; Valentin I. Zakharov; Boris I. Ionin ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 73 KB

Addition of secondary amines to alkynylphosphonates catalyzed by Cu(I) salts proceeds regio-and stereospecifically to form (E)-2-(dialkylamino)alkenylphosphonates. The E-configuration was proved by analysis of 13 C-31 P vicinal spin-spin coupling constants in the NMR spectra of the products and auth