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Addition of Phosphanes and Phosphites to Trifluoromethyl-Substituted 2-Aza-1,3-butadienes

โœ Scribed by Dr. Klaus Burger; Dipl.-Chem. Josef Fehn; Josef Albanbauer; Josef Friedl


Publisher
John Wiley and Sons
Year
1972
Tongue
English
Weight
195 KB
Volume
11
Category
Article
ISSN
0044-8249

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ses. Their relative total energies are 0, 0.4, 4.4 and -3.6 kcalmol-I , respectively.1111 Although the difference in energy between the (q2-0,C-HNCO)(q2-C,N-HNCO) and (q2-C,N-HNCO), isomers is small, the calculations are inconsistent with the observed structure. Next, we used molecular mechanics ca