Addition of Methyl Radicals to Isolated, Conjugated and Cumulated Dienes
β Scribed by Rajbenbach, A.; Szwarc, M.
- Book ID
- 120145058
- Publisher
- The Royal Society
- Year
- 1959
- Tongue
- English
- Weight
- 615 KB
- Volume
- 251
- Category
- Article
- ISSN
- 0962-8444
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π SIMILAR VOLUMES
The reaction of methyl radicals (Me) with hexafluoroacetone (HFA), generated from ditertiary butyl peroxide (dtBP), was studied over the temperature range of 402-433 K and the pressure range of 38-111 torr. The reaction resulted in the following displacement process taking place: where TFA refers t
The addition of methyl radicals to tetrafluoroethylene in the gas phase has been studied over the temperature range 8O-18O0C, using a material balance method. CH, + C,F4 -+ CH,C,F, Arrhenius parameters of 1011.95\*0.23 (mole-l cm3 sec-l) and 5.7 f 0.4 (kcal/mole) have been measured for the addition
## Abstract The addition of methyl radicals to hexafluoropropylene has been studied over the temperature range 81Β°β203Β°C using a massβbalance technique involving the photolysis of biacetyl in the presence of hexafluoropropyleneβisobutane mixtures. For the reaction the rate constant is given by th