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Addition of hydrogen halides to fluoro olefins

โœ Scribed by I. L. Knunyants; V. V. Shokina; N. D. Kuleshova

Book ID
112434746
Publisher
Springer
Year
1960
Tongue
English
Weight
168 KB
Volume
9
Category
Article
ISSN
1573-9171

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๐Ÿ“œ SIMILAR VOLUMES

Polar Addition of Hydrogen Halides onto
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Various ~truciures have been proposed for the interniediates of cktrophilic additions onfo olefrns; these inclirrle halonium ions, classical carboiium ions, r;-complexes (i. e. rionclassical carbonium ions), and Ti;-comple.ws with back-coordination. I t is shown here that it is impossible to use any

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The free radical addition of TFE and HFP to hydroxyl ended p-THF and p-ethyleneglycol (PEG) will be described. Under the reaction conditions the fluoro-olefins react with the hydroxyl groups of PEG but not with those of p-THF. The reason for this interesting difference and the products resulting fro