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Addition of Ethyl Bromodifluoroacetate to Lactones: Reactivity and Stereoselectivity.

✍ Scribed by Ana B. Cuenca; Francois D'Hooge; Vanessa Gouge; Geraldine Castelot-Deliencourt; Hassan Oulyadi; Eric Leclerc; Philippe Jubault; Xavier Pannecoucke; Jean-Charles Quirion


Book ID
101985515
Publisher
John Wiley and Sons
Year
2006
Weight
35 KB
Volume
37
Category
Article
ISSN
0931-7597

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The kinetics o f addition of a number of ortho-. rneta-, and para-substituted benzylarnines to ethyl a-cyanocinnamate [ECC) in acetonitrile have been studied. T h e reaction is First-order with respect to the amine and ECC. The rates of reaction of rneta-and para-substituted benzylamines showed exce