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Addition of compounds of alkoxy antimony(V) tetrachlorides with some phosphoryl and amine-oxide ligands

✍ Scribed by Ram Chand Paul; Harmeet Madan; S.L. Chadha


Book ID
118910428
Publisher
Elsevier Science
Year
1974
Weight
238 KB
Volume
36
Category
Article
ISSN
0022-1902

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Adducts of Niobium (V) and Tantalum (V)
✍ Christian M. P. Favez; AndrΓ© E. Merbach πŸ“‚ Article πŸ“… 1977 πŸ› John Wiley and Sons 🌐 German βš– 414 KB

The ligand exchange MX5 . L + \*L 8 MX, . \*L + L for the octahedral adducts MX, . L, in an inert solvent (CH2CI2 or CHCI,) with neutral ligands, proceeds via a dissociative D mechanism when M = Nb, X = C1 and L= phosphoryl compound. A dissociative interchange Id mechanism is suggested when M = N b