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Addition of bromotrichloromethane to methyl crotonate in the presence of various initiating systems

โœ Scribed by R. Kh. Freidlina; T. A. Pudova; F. K. Velichko

Book ID
112438012
Publisher
Springer
Year
1974
Tongue
English
Weight
294 KB
Volume
23
Category
Article
ISSN
1573-9171

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The addition of lithium diorganocuprates, (LiR2Cu)2, to a.,@-unsaturated carbonyl compounds in diethyl ether generally gives high yields of 1,4-addition products. 1 We are presently studying the possibility of asymmetric induction in the 1,4-addition of chiral organocuprates, (LiRR\*Cu)2,2 to a,@-un