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Addition of bromine to medium-ring allenes and acetylenes

โœ Scribed by C.B. Reese; A. Shaw

Book ID
104248418
Publisher
Elsevier Science
Year
1971
Tongue
French
Weight
146 KB
Volume
12
Category
Article
ISSN
0040-4039

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Strain and Reactivity: Electrophilic Add
Strain and Reactivity: Electrophilic Addition of Bromine and Tribromide Salts to Cyclic Allenes
โœ Cinzia Chiappe; Antonietta De Rubertis; Heiner Detert; Dieter Lenoir; Chaitanya ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 345 KB ๐Ÿ‘ 1 views

The kinetics and the products of the bromination of several cyclic allenes, from C 9 to C 13 (1 a ยฑ e), with tetrabutylammonium tribromide (TBAT) and Br 2 have been investigated in 1,2-dichloroethane (DCE) and methanol. The first product of the interaction between the allene and Br 2 is a 1:1 p comp