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Addition of Alkyl Radicals to Transition-Metal-Coordinated CO: Calculation of the Reaction of [Ru(CO) 5 ] and Related Complexes and Relevance to Alkane Carbonylation

✍ Scribed by Hasanayn, Faraj; Nsouli, Nadeen H.; Al-Ayoubi, Adnan; Goldman, Alan S.


Book ID
126790844
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
417 KB
Volume
130
Category
Article
ISSN
0002-7863

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## Abstract The formation of a ternary complex between phenols, Co (II)‐acetylacetonate and molecular oxygen has been established at ambient temperature and in non‐polar solvents. After intramolecular electron transfer the transient magnified image radical enhances the homolytic scission of the ο£ΏOο£Ώ