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Addition of a methylene group across the ester carbonyl function

โœ Scribed by Giancarlo Verardo; Paolo Strazzolini; Angelo G. Giumanini

Book ID
104227697
Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
139 KB
Volume
28
Category
Article
ISSN
0040-4039

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Coupling of two phosphaalkynes via a car
Coupling of two phosphaalkynes via a carbonyl group in the addition across a rhrh double bond
โœ Peter B. Hitchcock; Mohd Jamil Maah; John F. Nixon ๐Ÿ“‚ Article ๐Ÿ“… 1991 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 728 KB

## Abstract Phosphaalkynes, RC๏ฃฝP (R = Bu^t^, Adamantyl), add across the Rh๏ฃพRh double bond of [Rh~2~Cp(CO)~2~] to give either [Rh~2~Cp(ฮผโ€CO)(COPCR)] or [Rh~2~Cp(CO){PCRC(O)CRP}] depending on the stoichiometry of the reaction (Cp\* = ฮท^5^โ€C~5~Me~5~). The structures of these complexes have been elucid