Addition des nitrenes sur les ethers vinyliques cycliques. Application a la synthese d'aminosucres.

✍ Scribed by E Kozlowska-gramsz; G Descotes

• Publisher: Elsevier Science
• Year: 1981
• Tongue: French
• Weight: 211 KB
• Volume: 22
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(01)90155-8

✦ Synopsis

The stereochemistry of the photochemical addition of nitrenes to cyclic vinylethers is reported. The application of this reaction to unsaturated sugars offers a synthesis of aminosugars.