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Addition and insertion reactions of phenylnitrenoid with aromatic substrates. Synthesis of 1-phenyl-1H-azepine

✍ Scribed by Richard J. Sundberg; Richard H. Smith Jr.

Book ID
104247344
Publisher
Elsevier Science
Year
1971
Tongue
French
Weight
162 KB
Volume
12
Category
Article
ISSN
0040-4039

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## Abstract The reactions of 3‐phenyl‐1‐azabicyclo[1.1.0]butane with __Ξ±__‐chlorosulfenyl chlorides and sulfinyl chlorides lead to the corresponding sulfenamides and sulfinamides, respectively, which possess an azetidine ring. It is proposed that a two‐step mechanism occurs involving an intermediat