Acylation Studies. II. The Condensation of γ-Butyrolactone and γ-Valerolactone with Methyl Ketones
✍ Scribed by Cannon, George W.; Casler, James J.; Gaines, Walter A.
- Book ID
- 121399038
- Publisher
- American Chemical Society
- Year
- 1952
- Tongue
- English
- Weight
- 477 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0022-3263
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📜 SIMILAR VOLUMES
## Abstract The free‐radical copolymerization propagation kinetics of the bio‐renewable monomer __γ__‐methyl‐__α__‐methylene‐__γ__‐butyrolactone (MeMBL) with styrene (ST) and with methyl methacrylate (MMA) have been investigated by the pulsed laser polymerization (PLP)—size exclusion chromatography
## y-Vinyl-y-butyrolactone a& &vinyl-A-valeroZactone react regio-and stereosetectively with Grignard reagents in the presence of a copper(I) catalyst or with cliorganocuprates to afford IE)-4-and (El-S-alkenoic acids, respectively, in high yields. Synthetic utility of the former reaction is demons