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Acylation. Part XXI. Kinetics and mechanism of the hydrolysis of acyl cyanides

โœ Scribed by Hibbert, F.; Satchell, D. P. N.

Book ID
121397741
Publisher
Royal Society of Chemistry
Year
1967
Weight
947 KB
Category
Article
ISSN
0045-6470

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Kinetics of the acyl migration in some a
Kinetics of the acyl migration in some adducts of acyl-1, 4-benzoquinones: Part I
โœ Abdul Majeed Dabbagh; Raad Al-Hamdany ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 449 KB

The rates of migration of acetyl, propionyl, isobutyryl, and benzoyl substituent in Diels-Alder adducts of' acyl-1, 4-benzoquinones, (enediones), (I), to form the corresponding 2-acyl hydroquinones, (II), in 50% (v/u) ethanolic pyridine have been studied in detail. Rate dependence on pyridine concen