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Acylation of Benzene Compounds with Iodine as a Catalyst

✍ Scribed by Chodroff, Saul; Klein, Howard C.


Book ID
111917294
Publisher
American Chemical Society
Year
1948
Tongue
English
Weight
271 KB
Volume
70
Category
Article
ISSN
0002-7863

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A new type of fluoride ion catalyzed allylation agent, o-bis(allyldimethylsilyl)benzene (la)and bis(allyidimethylsilyl)methane (lb), can be successfully utilized for various carbonyi substrates. The rate acceleration is ascribable to the shift of equilibrium to complex with Bu4NF by the favorable ch