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Acylation of Amines with 5-Phenyltetrazol-2-ylacetyl Chloride

โœ Scribed by S. M. Putis; V. Yu. Zubarev; V. S. Poplavskii; V. A. Ostrovskii

Book ID
111577873
Publisher
Springer US
Year
2004
Tongue
English
Weight
218 KB
Volume
40
Category
Article
ISSN
0009-3122

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Regioselective Acylation of Heterocyclic Ketene Aminals with Acetyl Chloride. -Acylation of ketene aminals (I) affords exclusively the N-acylated products (IV), while in the presence of triethylamine and Hg(CN)2 the C-acylated products (III) predominate together with (IV) as minor products. The (E)