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Acylation of a novel quinoxalinyl substituted pyrazole derivative. synthesis, quantum chemistry calculations, and x-ray structure analysis

✍ Scribed by Barbara Matuszczak; Thierry Langer; Kurt Mereiter


Publisher
Journal of Heterocyclic Chemistry
Year
1998
Tongue
English
Weight
240 KB
Volume
35
Category
Article
ISSN
0022-152X

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✦ Synopsis


The preparation of (N)-acetylpyrazolyl-quinoxalines and results of semiempirical MO calculations are presented. The structure determination of the isomers 3a,b was achieved by X-ray analysis.


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## Abstract 3,4‐Diazabicyclo[4.3.0]non‐2‐ene and __N,N'__‐azo‐3‐azabicyclo[3.3.0]octane are the main products of the oxidation of __N__‐amino‐3‐azabicyclo[3.3.0]octane by chloramine. These new compounds have been isolated and characterized. A structural study has been performed with the goal of est