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Acylated 2-oxoglycosyl bromides: Exploration of their reaction potential

โœ Scribed by Frieder W. Lichtenthaler; Sabine Schwidetzky; Katsumi Nakamura

Book ID
108382419
Publisher
Elsevier Science
Year
1990
Tongue
French
Weight
267 KB
Volume
31
Category
Article
ISSN
0040-4039

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Indium-mediated reaction of acyl cyanides 1 with prop-2-ynyl bromides 2 in aqueous media occurs regioselectively to afford either allenic 3 or propargylic ketones 4 depending on the g-substituent of the prop-2-ynyl bromide under the mild conditions.