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Acyl CO bond cleavage in Cp*2TiCOR compounds: formation of benzene derivatives by Cp*-ring expansion involving incorporation of the acyl carbon atom (Cp* = η5-C5Me5)

✍ Scribed by Eric J.M. de Boer; Jan de With

Book ID
103221763
Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
343 KB
Volume
320
Category
Article
ISSN
0022-328X

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📜 SIMILAR VOLUMES

Formation of .eta.1-iminoacyl compounds
Formation of .eta.1-iminoacyl compounds by insertion of isonitriles into pentamethylcyclopentadienyl-tetramethylfulvene compounds of titanium and zirconium. Intramolecular C-H activation of a pentamethylcyclopentadienyl group to give a tridentate ligand with two bridged cyclopentadienyl rings and a titanium-vinyl bond in the bridge. Molecular structure of [cyclic][.eta.5:.eta.1:.eta.5-C5Me4CH2C(NHXyl):CN(Xyl)CH2C5Me4]TiCl and [cyclic]Cp*[.eta.5:.eta.1-C5Me4CH2C(:NXyl)C(:NXyl)]ZrCl (Xyl=2,6-Me2C6H3)
✍ Fandos, Rosa.; Meetsma, Auke.; Teuben, Jan H. 📂 Article 📅 1991 🏛 American Chemical Society 🌐 English ⚖ 916 KB