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Acyclic stereocontrol through the metalla-claisen rearrangement. Part I

✍ Scribed by Ilane Marek; Jean-Michel Lefrançois; Jean F. Normant


Book ID
108381452
Publisher
Elsevier Science
Year
1991
Tongue
French
Weight
207 KB
Volume
32
Category
Article
ISSN
0040-4039

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Acyclic stereocontrol via the claisen re
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The unique bicyclic ring systen of tirandamycin (8&),' an acyltetramic acid antibiotic, has inspired several synthetic efforts directed towards its total synthesis. Tirandamycic acid (a), a degradation product of tirandamycin, has been synthesized by Ireland in optically active form frolrl D-glucose