The effect of polyelectrolyte cation specificity, charge density, and conformation on the interaction between furcelleran, , , and -carrageenan, respectively, and amitriptyline, an amphiphilic cationic drug molecule, was studied by means of a dialysis equilibrium technique. The carrageenans used in
✦ LIBER ✦
Activity coefficients of counterions and conformation in kappa-carrageenan systems
✍ Scribed by C. Rochas; M. Rinaudo
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1980
- Tongue
- English
- Weight
- 496 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0006-3525
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✦ Synopsis
Abstract
The optical rotation and the conductivity of kappa‐carrageenans in aqueous solution have been investigated as functions of temperature in the presence of various electrolytes. The activity coefficients of sodium and potassium have been determined and correlated with the conformation. The potassium activity coefficient under ordered conformation is in agreement with a mechanism of dimerization.
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The effect of polyelectrolyte counterion
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🏛
Wiley (John Wiley & Sons)
🌐
English
⚖ 133 KB
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